a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(n_{H_2}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\Rightarrow m_{Al}=0,4.27=10,8\left(g\right)\)

b, \(n_{HCl}=2n_{H_2}=1,2\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{1,2.36,5}{250}.100\%=17,52\%\)

c, m _{dd sau pư} = 10,8 + 250 - 0,6.2 = 259,6 (g)

d, \(n_{AlCl_3}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,4.133,5}{259,6}.100\%\approx20,57\%\)

Theo gt ta có: $n_{Al}=0,1(mol)$

a, $2Al+6HCl\rightarrow 2AlCl_3+3H_2$

b, $\Rightarrow n_{H_2}=0,15(mol)\Rightarrow V_{H_2}=3,36(l)$

c, Ta có: $n_{HCl}=0,3(mol)\Rightarrow m_{HCl}=10,95(g)\Rightarrow \%m_{ddHCl}=219(g)$

d, Bảo toàn khối lượng ta có: $m_{dd}=221,4(g)$

$\Rightarrow \%C_{AlCl_3}=6,02\%$

a, Ta có: \(m_{H_2SO_4}=500.5,88\%=29,4\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

______0,2________0,3_______0,1______0,3 (mol)

\(m_{Al}=0,2.27=5,4\left(g\right)\)

\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)

b, Ta có: m _{dd sau pư} = 5,4 + 500 - 0,3.2 = 504,8 (g)

\(\Rightarrow C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{504,8}.100\%\approx6,77\%\)

\(a)n_{H_2SO_4}=\dfrac{500.5,88}{100.98}=0,3mol\\2 Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

0,2          0,3               0,1                0,3

\(m_{Al}=0,2.27=5,4g\\ V_{H_2\left(đktc\right)}=0,3.22,4=6,72l\\ b)C_{\%Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{500+5,4-0,3.2}\cdot100=6,77\%\)

n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)

n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)

       \(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)

bđ    0,1............0,5

pư    0,1............0,3..................0,1

spu   0 ................0,2................0,1 

=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O

m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)

m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)

m dd = \(490+10,2=500,2g\)

% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)

% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)

\(a) 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ b) n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ n_{Al} = \dfrac{2}{3}n_{H_2} = 0,2(mol)\\ m_{Al} = 0,2.27 = 5,4(gam)\\ c) n_{HCl\ pư} = 2n_{H_2} = 0,6(mol)\\ n_{HCl\ đã\ dùng} = \dfrac{0,6}{80\%} = 0,75(mol)\\ m_{dd\ HCl} = \dfrac{0,75.36,5}{54,75\%} = 50(gam)\)

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\n_{H_2SO_4}=\dfrac{294\cdot10\%}{98}=0,3\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,3}{3}\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,075\left(mol\right)=n_{H_2SO_4\left(dư\right)}\\n_{H_2}=0,225\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,225\cdot22,4=5,04\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,075\cdot342=25,65\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,075\cdot98=7,35\left(g\right)\\m_{H_2}=0,225\cdot2=0,45\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=297,6\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{25,65}{297,6}\cdot100\%\approx8,62\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{7,35}{297,6}\cdot100\%\approx4,47\%\end{matrix}\right.\)

a) 2Al + 6HCl --> 2AlCl₃ + 3H₂

b) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\); n_HCl = 0,5.2 = 1 (mol)

Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{1}{6}\) => Al hết, HCl dư

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

             0,1->0,3---->0,1---->0,15

=> V_H2 = 0,15.22,4 = 3,36 (l)

c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,5}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{1-0,3}{0,5}=1,4M\end{matrix}\right.\)

2Al+3H2SO4->Al2(SO4)3+3H2

0,1----------------------0,075----0,15

n H2=0,15 mol

=>mAl=0,1.27=2,7g

=>m Al2(SO4)3=0,075.342=25,65g

a) PTHH: \(2Al+3H_2SO_2\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(n_{Al}=\dfrac{2}{3}.0,15=0,1\left(mol\right)\)

\(m_{Al}=0,1.27=2,7\left(g\right)\)

c) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)

\(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)

2Al+3H2SO4->Al2(SO4)3+3H2

0,1----------------------0,075----0,15

n H2=0,15 mol

=>mAl=0,1.27=2,7g

=>m Al2(SO4)3=0,075.342=25,65g

Câu 1 :

a)  PTHH : 

 \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\) (1) 

  \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)(2)

b) Ta có : \(n_{Zn}=\frac{3,5}{65}\approx0,054\left(mol\right)\)

Theo phương trình hóa học (1) :

\(n_{H_2}=n_{Zn}\approx0,054\left(mol\right)\)

\(\Rightarrow V_{H_2}\approx0,054\cdot22,4=1,2096\left(l\right)\)

c) Theo phương trình hóa học (2), ta có:

\(n_{Cu}=n_{H_2}\approx0,054\left(mol\right)\)

\(\Rightarrow m_{Cu}\approx0,054\cdot64=3,456\left(g\right)\)

Bài 2:

a) Ta có : \(n_{Al}=\frac{2,7}{27}=0,1\left(mol\right)\); \(n_{HCl}=\frac{200\cdot7,3}{100\cdot36,5}=0,4\left(mol\right)\)

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Theo phương trình hóa học : \(n_{H_2}=\frac{3}{2}n_{Al}=\frac{3}{2}.0,1=0,15\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)

b) Theo phương trình hóa học , ta có : \(n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\)

\(\Rightarrow m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\)

Lại có: \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)

Áp dụng định luật bảo toàn khối lượng, ta có:

\(m_{Al}+m_{dd_{HCl}}=m_{dd_{AlCl_3}}+m_{H_2}\)

\(\Leftrightarrow2,7+200=m_{dd_{AlCl_3}}+0,3\)

\(\Leftrightarrow m_{dd_{AlCl_3}}=202,4\left(g\right)\)

Vậy \(C\%_{dd_{AlCl_3}}=\frac{13,35}{202,4}\cdot100\%\approx6,6\%\)